With my '05, I ran the 35x12.50-18 Toyo MTs on the stock 18"x8" wheel that came on that truck. The set I put on were used and down to about 35% when I installed them, and they liked 65 in the front just fine for my driving style which is a bit aggressive into corners. But 65 in the rear towing my 11k 5th wheel (scaled at 5000lbs on the front axle, 5000lbs on the rear axle, 10,000lbs on the trailer axles loaded up with the family and out stuff) I centered out the rears in 10k miles of towing a couple summers back, and still got another 15k miles out of the fronts from that set. Having learned that, even towing I won't be running more than 50-55psi in the rears running the same size tires on my E99 with the '05 axles and '05 18x8 wheels.
With your tire being a 33" diameter on a 22" wheel, the width will play into the pressure a bit too. A wider (10.5-12") wheel should need a bit more pressure than a narrower (8.5-10") wheel to keep the tread flat as the beads and sidewalls spread.
Sent by my right thumb!